4-[4-(Methylsulfanyl)phenyl]-6-phenyl-2,2′-bipyridine
نویسندگان
چکیده
The structure of the title compound, C(23)H(18)N(2)S, is revealed by X-ray diffraction to be almost planar over all four aromatic rings; the pendant rings are at angles of 10.18, 14.12 and 15.42° relative to the central pyridine ring for the 4-methylsulfanyl, 2-pyridyl and 6-phenyl rings, respectively. The 2,6-aromatic substituents are disordered over two sites in a 0.6:0.4 occupancy ratio.
منابع مشابه
Bis{μ-2-[3-carboxylatomethyl-4-(phenylsulfanyl)phenyl]propanoato-κ4 O,O′:O′′,O′′′}bis[(2,2′-bipyridine-κ2 N,N′)cadmium]
In the title complex, [Cd(2)(C(17)H(14)O(4)S)(2)(C(10)H(8)N(2))(2)], which was hydro-thermally synthesized, the Cd(II) cation is hexa-coordinated in a distorted octa-hedral geometry by two N atoms from a 2,2'-bipyridine ligand and by four O atoms from two different 2-[3-carboxyl-atometh-yl-4-(phenyl-sulfan-yl)phen-yl]propano-ate ligands, forming a cyclic dimetallic complex.
متن کامل4-{Phenyl[4-(6-phenyl-2,2′-bipyridin-4-yl)phenyl]amino}benzaldehyde
The title mol-ecule, C35H25N3O, is a tri-phenyl-amine derivative with the 4-position substituted by an aldehyde group, and the 4'-position substituted by a 6-phenyl-2,2'-bi-pyridine group. The whole mol-ecule is non-planar and the dihedral angle between the core benzene and pyridine rings is 36.96 (5)°. The dihedral angle between the phenyl and benzaldehyde groups bonded to the amine N atom is ...
متن کامل2-Bromo-2-methyl-1-[4-(methylsulfanyl)phenyl]propan-1-one
In the title compound, C(11)H(13)BrOS, the thio-ether unit and the phenyl ring adopt an essentially planar conformation, with a maximum deviation of 0.063 Å. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds, extending in zigzag chains along the b axis. A weak intra-molecular C-H⋯Br hydrogen bond is also observed, which forms an S(6) ring motif.
متن کاملThienylpyridine-based cyclometallated iridium(III) complexes and their use in solid state light-emitting electrochemical cells.
The synthesis and characterization of four iridium(iii) complexes [Ir(thpy)2(N^N)][PF6] where Hthpy = 2-(2'-thienyl)pyridine and N^N are 6-phenyl-2,2'-bipyridine (1), 4,4'-di-(t)butyl-2,2'-bipyridine (2), 4,4'-di-(t)butyl-6-phenyl-2,2'-bipyridine (3) or 4,4'-dimethylthio-2,2'-bipyridine (4) are described. The single crystal structures of ligand 4 and the complexes containing the [Ir(thpy)2(1)](...
متن کامل(E)-1-[4-(Methylsulfanyl)phenyl]-3-phenylprop-2-en-1-one
In the title mol-ecule, C(16)H(14)OS, the dihedral angle between the phenyl and benzene rings is 3.81 (15)°. The H atoms of the central enone group are trans. The propenone unit makes dihedral angles of 11.73 (18) and 11.62 (17)° with the benzene and phenyl rings, respectively. The crystal structure is stabilized by weak C-H⋯O and C-H⋯π inter-actions.
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